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EN 10253-2 Type B Acids · Alkalis · Chlorides BASF · Dow · Evonik · Ineos

Chemical Process Pipe Fittings

EN 10253-2 Type B buttweld pipe fittings for chemical manufacturing — inorganic acids, organic acid processes, chloride-bearing chemical streams, alkali service, and mixed solvent environments. The chemical industry demands the widest material range: 316L for mild service through Hastelloy C-276 (PRE ~73) for the most aggressive reducing acid and mixed acid environments.

Material Selection by Chemical Service Environment

EnvironmentGradeW.Nr.Note
Dilute NaOH / KOH (caustic) — ambient316L1.4404316L adequate; Inconel 600 for hot concentrated caustic
Chloride-bearing process, ambient temp316L / Duplex 22051.4404 / 1.4462Grade by chloride concentration
Chloride process, elevated temperatureSuper Duplex 2507 / 254 SMO1.4410 / 1.4547254 SMO if above 250°C (duplex limit)
HCl (hydrochloric acid) — any concentrationHastelloy C-2762.4819No standard SS resists HCl; C-276 with 16% Mo is standard
H₂SO₄ reducing conditions / diluteHastelloy C-2762.4819Reducing dilute H₂SO₄ attacks SS; C-276 resists broadly
HNO₃ (nitric acid) — oxidising304L / 316L1.4307 / 1.4404Oxidising nitric acid compatible with austenitic SS
HNO₃ + HF (mixed pickling acid)Inconel 6252.4856HF attacks all SS; 625 resists both acids simultaneously
Phosphoric acid — moderate temp316L / Duplex 22051.4404 / 1.4462H₃PO₄ compatible at moderate concentration and temperature
Phosphoric acid — high temp or conc.Inconel 625 / C-2762.4856 / 2.4819Hot concentrated H₃PO₄ requires Ni alloy
FGD scrubber (SO₂ + HCl wet gas)Hastelloy C-2762.4819Combined wet SO₂ + HCl attacks all SS and duplex

Grade Profiles — Chemical Process

316L (1.4404)
PRE ~24 · Workhorse austenitic

Mild chloride, dilute alkali, many organic solvents, nitric acid service. UK/NL/Scandinavia/USA standard. Most widely specified SS in chemical plants.

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254 SMO (1.4547)
PRE ≥43 · 6% Mo · No sigma limit

Hot chloride processes above 250°C (where duplex is restricted), FGD, bleach, high-chloride scrubbing. Fully austenitic — no intermetallic ceiling.

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Inconel 625 (2.4856)
PRE ~51 · 9% Mo · Nb-stabilised

Mixed acid service (HNO₃ + HF), aggressive chloride at temperature, phosphoric acid (hot/concentrated), chemical waste with mixed corrodants.

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Hastelloy C-276 (2.4819)
PRE ~73 · 16% Mo · Reducing acids

HCl at any concentration, reducing H₂SO₄, mixed acid + chloride, FGD absorber, chemical waste incineration scrubbing. Highest PRE of any commercial alloy.

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Inconel 600 (2.4816)
Ni ≥72% · Caustic SCC immune

Hot concentrated caustic (NaOH/KOH) where austenitic SS suffers caustic SCC. Alumina (Bayer process) caustic evaporators, high-temp dry gas chemical piping.

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316Ti (1.4571)
PRE ~24 · Ti-stabilised · DE/IT standard

Equivalent to 316L for German, Austrian, Italian, and Central European chemical plant specifications. Same corrosion resistance — Ti stabilisation rather than low C.

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Chemical Industry Certification

EN 10204 3.1 standard. EN 10204 3.2 (TÜV) on request for critical service. PED 2014/68/EU and AD 2000-Merkblatt W0 compliant. Positive Material Identification (PMI) available. ATEX documentation on request.

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